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Sintesis Bio-Pelumas dari Minyak Limbah Ikan Patin dengan Pengaruh Kecepatan Pengadukan dan Suhu Reaksi

机译:搅拌速度和反应温度对from鱼废油合成生物润滑剂的影响

摘要

Bio-lubricant synthesis from catfish waste oil is purposed to modify the useless oil to be a bio-lubricant. That function\u27s is to protect the engine component from wear. Esterification with ethylene glycol toward acid from catfish waste oil hydrolysis with mole ratio 1:4 for 4 hours, with variation of temperature and mixing speed. The waste extracted by rendering, oil\u27s boiling point is 270oC, the viscosity is 15,69 mPa s. The oil hydrolyzed at 80 oC with adding of HCl concentrated catalyst 0,1% weight/weight for 8 hours and produce the acid. That\u27s polymerized by adding benzoyl peroxide as 0,2% for 5 hours at 120 oC. Then, polyestherification by adding ethylene glycol in mole ratios of 1:4, for 4 hours at 120 oC, 150 oC, 1800C, and mixing speed at 150 rpm, 180 rpm, and 210 rpm. The resulting has its density, it\u27s 0,942 gr/m, viscosity is 61,081 mPa.s, flame point is 290,5oC, boiling point is 290 oC with yield of 66,5%. The product has a commercial standard (density is 0,92 gr/ml and viscosity is >41,1 mPa.s). The best result from this research was obtained by mole ratio 1:4 for 4 hours; the mixing speed is 150 rpm at 150oC.
机译:由cat鱼废油合成生物润滑剂的目的是将无用的油改性为生物润滑剂。该功能是为了防止发动机部件磨损。在温度和混合速度不同的情况下,将cat鱼废油水解中的乙二醇酯化为酸,将其酯化为4个小时,持续4小时。提炼后的废物,油的沸点为270oC,粘度为15,69 mPa s。该油在80℃下通过添加0.1%(重量/重量)的HCl浓催化剂水解8小时,并产生酸。通过在120 oC下添加0.2%的过氧化苯甲酰5小时来聚合。然后,通过以1:4的摩尔比添加乙二醇,在120℃,150℃,1800℃和150 rpm,180 rpm和210 rpm的混合速度下进行4小时的聚醚化反应。所得物的密度为0,942 gr / m,粘度为61,081 mPa.s,燃烧点为290,5oC,沸点为290 oC,收率为66.5%。该产品具有商业标准(密度为0.92 gr / ml,粘度> 41.1 mPa.s)。该研究的最佳结果是通过摩尔比1:4持续4小时获得的。在150oC下的混合速度为150 rpm。

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